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Fuel Cell & Hydrogen

Adsorption and desorption under normal and high pressure. Reversibility. Storage efficiency. Thermal cycling. Thermal stability of materials.
The storage of hydrogen and the development of fuel cells are one of the main issues for the development of renewable energies in the next few years. Different groups of materials (nanotubes, nanofibers, zeolites, gas hydrates, metal hydrides...) are potential vectors for this hydrogen storage and are under investigation. Calorimetric and thermogravimetric techniques are ideal tools for this field of investigations.
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Different groups of materials have the potentiality to store and release hydrogen: - carbon : nanotubes and graphite nanofibers - other high surface area materials :
H2O-reactive chemical hydrides: zeolites, gas hydrates, metal oxide frameworks (MOFs)
thermal chemical hydrides
rechargeable hydrides borohydrides, alanates, amides. The R&D issues that can be followed by the calorimetric techniques are to find lower desorption temperatures, higher desorption kinetics, optimisation of the recharge time and pressure, heat management, cyclic life, optimisation of the storage capacity.
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Fuel Cell & Hydrogen
Calorimetric and thermogravimetric solutions: Sensys TG-DSC, C80, HP-MicroDSC, MultiHTC
SETARAM offers different thermogravimetric and calorimetric techniques for the investigation of hydrogen storage and the materials used in fuel cells. Investigations under high pressure of hydrogen are also possible with the DSC and calorimetric techniques.
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According to the type of applications, SETARAM can offer different solutions:
- the SENSYS TG-DSC is an ideal solution for the investigation of hydrogen desorption and adsorption under normal pressure in a large range of temperature (up to 820°C) - The Sensys High Pressure DSC is adapted for the investigation of hydrogen adsorption under pressure (up to 500 bar). For larger amounts of sample (up to 0,5ml), the HP-<b >MicroDSC is available especially for the investigation of hydrogen storage in gas hydrates in a limited range of temperature (-45°C to 120°C).
- The Calvet C80 calorimeter allows to investigate the desorption of hydrogen from solid materials with very large amounts of sample (up to 10 ml).
-The MultiHTC is a high temperature calorimeter that is suitable for the investigation of materials or solutions used for the electrolytes, such as molten carbonates and solid oxides used in the fuel cells.
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Some references
Some references X
Pacific Northwest National Laboratory (Richland, WA, USA)
UC Davis (CA, USA)
University of Central Florida (FL, USA)
University Freiberg (Germany)
Institut Recherche Catalyse (France)

An innovative line of Thermal Analyzers (-120 / 830°C) with 3D-Inside technology: DSC, High Pressure DSC, Robot DSC, TG-DSC-EGA

An innovative line of Thermal Analyzers (-120 / 830°C) with 3D-Inside technology: DSC, High Pressure DSC, Robot DSC, TG-DSC-EGA
 
The SENSYS evo offers the most precise DSC sensor together with a truly symmetrical microbalance to give YOU a combined TG-DSC system with totally unmatched performance. Additionally both measurement sensors are totally independent,so can be operated independently or simultaneously without compromising performance.
SENSYS evo can be used in various configurations:
- DSC in horizontal or vertical mode
- High Pressure DSC(up to 500 bars at 600°C)
- Robotic DSC, with 48 samples, even under pressure
- Simultaneous TG-DSC-coupling to gas analysis (BET, gas sorption, FTIR, MS)


Reaction, isothermal and scanning calorimeter (ambient to 300°C)

Reaction, isothermal and scanning calorimeter (ambient to 300°C)
 

C80


Using SETARAM's exclusive Calvet 3D calorimetric sensor, the C80 calorimeter is one of the most powerful, yet flexible calorimeters available.
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Mastering High Pressure DSC & Microcalorimetry up to 1000 bars - 14,500 psi

Mastering High Pressure DSC & Microcalorimetry up to 1000 bars - 14,500 psi
 

HP Micro DSC


Setaram sells the Gas Hydrates technology UNDER IFP's LICENCE (French Petroleum Industry) PA WO 2006/129018 A2 DSC measurement under very high pressure is of major importance for materials investigation and processes, to study PVT properties, in different fields such as energy (Gas hydrates), food, polymers, process safety, etc. SETARAM's latest innovation is the Ultra High Pressure Gas Panel that allows DSC and calorimetry measurements up to 1000 bar.
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High-performance modular thermal analyzers (ambient / 2400°C)

High-performance modular thermal analyzers (ambient / 2400°C)
 
Widest temperature range (-150 / 2400°C) on the market
Modularity: the different modules DTA, DSC, TGA, TMA can be adapted interchangeably around the same structure
Measurement performance: satisfy unique resolution, precision and sensitivity criteria
SETSYS Evolution is today the state-of-the-art in research-grade thermal analyzers.
It includes:
-SETSYS Evolution DTA (up to 2400°C), DSC (up to 1600°C)
-SETSYS Evolution TGA
-SETSYS Evolution simultaneous TGA-DTA/DSC-EGA
-SETSYS Evolution TMA


TGA, DTA, DSC and Simultaneous TGA-DTA, TGA-DSC from ambient to 1600°C

TGA, DTA, DSC and Simultaneous TGA-DTA, TGA-DSC from ambient to 1600°C
 

LABSYS evo


- Coupling to gas analysis (FTIR, MS) - New 3D high-precision Cp sensor - Cp measurement within 2 % up to 1600 °C - Calisto software LABSYS evo offers TGA with simultaneous DTA or DSC and Cp measurement within the temperature range of ambient to 1 600 °C. The LABSYS evo features a NEW high performance top loading balance and a unique 3D high-precision (Calvet type) Cp rod. Thanks to its unique ergonomic design and market leading Calisto software the LABSYS evo offers you the most easy-to-use Thermal Analysis system with uncompromised performance.
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A fully automated Sieverts instrument for measuring Hydrogen sorption properties of materials

A fully automated Sieverts instrument for measuring Hydrogen sorption properties of materials
 

PCTPro-2000


This quality instrument is specifically designed for high precision measurements over a wide range of sample sizes, pressures and temperatures
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Stand-alone High Pressure Mass Spectrometer for gas composition analysis from 200 bar to 10-8 mtorr

Stand-alone High Pressure Mass Spectrometer for gas composition analysis from 200 bar to 10<sup >-8</sup> mtorr
 

RGAPro


The RGAPro is a residual gas analyzer designed to work with the PCTPro-2000 or any other gas process for real-time compositional analysis of a wide range of gases.
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 Application Notes
Combined calorimetry and hydrogen sorption measurements on LaNi5

Combined mass spectrometry and sorption measurements on mixed Alanate-Amide hydrogen storage materials

Direct Van’t Hoff measurement

Measurement of small hydrogen sorption quantities by the Sievert’s method

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 See articles


 Brochure
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 Link
Development of new thermogravimetric and calorimetric technique for the determination of energetics, thermodynamics and kinetics of hydrogen storage in various materials


 Hydrogen Storage Materials
PCTPro-SIGMA-ALDRICH-Hydrogen-Storage-Materials.pdf
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